• 不 限
  • 期刊论文
  • 硕博论文
  • 会议论文
  • 报 纸
  • 英文论文
  2. 您的位置
  3. 首页
  4. 会议论文
  5. CrⅢ and CuⅠ-mediated in situ generation of imidazole ring from the coupling of picolinaldehyde and a

CrⅢ and CuⅠ-mediated in situ generation of imidazole ring from the coupling of picolinaldehyde and a

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户：emmajqf
【摘 要】
：
Two coordination complexes of compositions [Cr3(L)3Cl6](1)and [Cu4(L)2Br2]n(2)(HL = 2,2,2-(1H-imidazole-2,4,5-triyl)tripyridine)were prepared.The HL ligand was generated by metal-mediated solvertherma
【作 者】
：
秦亚茹 陈砚美 刘金娜 李亚红 刘玮 李武 
【出 处】
：
第九届全国无机化学学术会议
【发表日期】
：
2015年7期
【关键词】
：
Copper(Ⅰ) in situ metal/ligand reaction Ketalization 
下载到本地 , 更方便阅读
下载此文 赞助VIP
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
　　Two coordination complexes of compositions [Cr3(L)3Cl6](1)and [Cu4(L)2Br2]n(2)(HL = 2,2,2-(1H-imidazole-2,4,5-triyl)tripyridine)were prepared.The HL ligand was generated by metal-mediated solverthermal in situ metal-ligand reaction among picolinaldehyde,ammonium acetate and metal ions.
其他文献
Ionic Compounds with 5-Ferrocenyltetrazolate anion.Synthesis, Structures and Catalytic Effects on Th
The development of new types of ferrocene-based combustion modifiers for composite solid propellants is a continuing work in the field of burning-rate(BR)catalysts.
会议
Ionic ferrocenyl compound1-Ferrocenyltetrazolate anionCombustion catalytic eff
Comparision of Cyclic Voltammetry between the bound mono-olefin with nickel bisdithiolene complexes
金属化合物11 可以进行如有机合成中两个单烯之间的[2+2]加成,如下图所示:化合物11 的相关化合物6 可以经历与单烯和双二硫纶镍之间的类似循环伏安图:二聚体还原得一个电子时循环伏安吸收峰很小.估计这两系列金属化合物在循环伏安条件下的第一个电子还原均经历了分子内氧化-还原反应过程.
会议
Polyoxovanadate Templated Silver(Ⅰ)-thiolate Cluster
Recently,increasing attention has been attracted by the high-nuclearity metal clusters not only because of their structural aesthetics,but also owing to their intriguing properties and potential appli
会议
Template anionsSilver(Ⅰ)-thiolatePolyoxovanadate
Estrogen Induced Anticancer Silver(Ⅰ)-alkynyl Cluster
Silver-alkynyl clusters have been studied extensively not only due to their fascinating structures but also owing to their potentially luminescent and catalytic appications.[1-3] However,there remains
会议
EthisteroneSilver(Ⅰ)-alkynyl clusterAnticancer
Oxidation of Benzyl Alcohols and Benzaldehyde via a Water-Soluble Cu(Ⅱ)/Calix[4]arene Complex Cataly
Metal complexes of calixarenes exhibits excellent catalytic performances in various reactions [1,2],but are less reported in the copper-catalyzed oxidation reactions.Relative to common O-donor ligands
会议
Calix[4]areneCopper(Ⅱ) complexOxidationBenzyl alcoholsBenzaldehyde
Design of Further Functionalization of the Bound Mono-olefin with Nickle Bis(dithiolene)Complexes Me
Halogenation of olefin is usually difficult.But the covalent bond instead of the olefinic bond isformed when mono-olefin reversibly bonds with nickle bis(dithiolene) complexes(the boundreaction can be
会议
1,2,4-Diazaphospholide Complexes of Yttrium(Ⅲ),Dysprosium(Ⅲ),Erbium(Ⅲ),and Europiu(Ⅱ):Synthesis,Stru
A few of novel heteroleptic,charge-separated heterobimetallic,and polymeric alkali metal ate complexes of 1,2,4-diazaphospholide yttrium(Ⅲ),dysprosium(Ⅲ),erbium(Ⅲ),and europium(Ⅱ)were prepared via the
会议
rare earth elements124-diazaphospholidemetallodendrimercharge-separated het
A 1,2,4-Diazaphospholyl Radical and Its Associated Dimer with Nitrogen-Phosphorus Coupling:Synthesis
The oxidation of 1,2,4-diazaphospholide potassium(K+[2–])with oxidants produced a neutral 1,2,4-diazaphospholyl radical(2(·))which was evidenced by formation of a spin adduct DMPO[2(·)].Radical 2(·)is
会议
124-diazaphospholideN-ligandradicalfive-membered ringradical dimerization
Titanium complexes supported by pyrrolyl ligand as catalysts for hydroamination and polymerization r
Three complexes of compositions TiL2(NMe2)2(1),TiL2(NEt2)2(2)and TiL2(OiPr)2(3)(HL = 3-(1H-pyrrol-2-yl)imidazo[1,5-a]pyridine)has been synthesized.All complexes have been characterized by elemental an
会议
TitaniumHydroaminationPolymerizationCytotoxicity
Bis(2-cycloazylindolyl)titanium complexes:Synthesis,characterization and the catalytic behaviors tow
The ligands 2-(pyrazol-1-yl)-1H-indole(HL1)and 2-(1,2,4-triazol-1-yl)-1H-indole(HL2)individually reacted with Ti(NMe2)4 in tetrahydrofuran to form two titanium amide complexes.
会议
TitaniumCatalysisEthylene dimerization