Dramatic Enhancement of Catalytic Activity on Titanosilicate Molecular Sieves Induced by Cation-π In

来源 :2014 International Symposium on Resource Chemistry 2014(2014 | 被引量 : 0次 | 上传用户：jay12

【摘要】

：

Titanosilicate molecular sieves,exemplified by TS-1 and Ti-MCM-41,are known as efficient catalysts for the selective oxidation of a variety range of hydrocarbon

【作者】

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Yasutaka Kuwahara Hiromi Yamashita

【机构】

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DivisionofMaterialsandManufacturingScience,GraduateSchoolofEngineering,OsakaUniversity,Osaka,565-087

【出处】

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2014 International Symposium on Resource Chemistry 2014(2014

【发表日期】

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2014年9期

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Titanosilicate molecular sieves,exemplified by TS-1 and Ti-MCM-41,are known as efficient catalysts for the selective oxidation of a variety range of hydrocarbons using H2O2.To date,tremendous effort has been made to improve their catalytic activities;for example,controlling crystal architecture,changing electric charge density of the surface as well as direct/post-synthetic silylation of their surfaces using organo-/fluoro-silanes.

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