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Amphiphilic diblock copolymer (poly(ethylene oxide-b-ethylene), PEO-b-PE) as organic templates for the synthesis of mesoporous silicas via the evaporation-induced self-assembly (EISA) approach.The mesophase transformation of mesoporous silica with the variation of hydrochloric acid or TEOS content was characterized by transmission electron microscopy (TEM) and small angle X-ray scattering (SAXS) analyses.