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分别以Al2O3,TiO2,CeO2,ZrO2为水解活性组分,并浸渍不同的碱溶液KOH,NaOH,K2CO3,Na2CO3,制备了低温一体化脱除二硫化碳催化剂,并考察了低温下一体化催化脱除二硫化碳的可行性。通过无氧、有氧试验设计以及反应产物分析,推断出耦合催化脱除二硫化碳的宏观反应历程,认为二硫化碳的水解是催化耦合过程的控制步骤。同时分析了温度、硫浓度、相对湿度和氧硫比操作条件对催化耦合脱除二硫化碳的影响。在操作条件为反应温度125℃,相对湿度3％,氧硫比2和空速2797 h-1下该催化剂工作硫容可达到2．51 mg·g-1。
The catalysts for the synthesis of carbon disulfide were synthesized by impregnating Al2O3, TiO2, CeO2 and ZrO2 respectively with different alkali solutions KOH, NaOH, K2CO3 and Na2CO3. The catalytic effect of carbon disulfide Feasibility. Through the anaerobic and aerobic experimental design and the analysis of the reaction products, the macroscopic reaction course of the coupling catalytic removal of carbon disulfide was deduced, and the hydrolysis of carbon disulfide was considered as the control step of the catalytic coupling process. The effects of operating conditions such as temperature, sulfur concentration, relative humidity and oxygen to sulfur ratio on the catalytic coupling to remove carbon disulfide were also analyzed. The working sulfur capacity of this catalyst can reach 2.51 mg · g-1 under the operating conditions of reaction temperature 125 ℃, relative humidity 3%, oxygen-sulfur ratio 2 and space velocity 2797 h-1.