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In this paper,the dose rate of some provinces is introduced,such as Guangxi,Guangdong,Guizhou,Hunan,Hubei,Shanxi and Shandong (It is a key of the database system and describes the attributes of 1 composed samples for 4km2 or for 16km2 including sample ID,geologic code,center coordinates of a composed sample,terrestrial gamma-ray in air 1 meter above the ground data and more.) which is polluted by associated minerals with radioactivity.We summarize the distribution of these mines in seven provinces and select some typical points to analysis.Then we use the environment monitoring data of the enterprises and the distribution maps of terrestrial γ radiation dose of these provinces to discuss the relationship of associated minerals and natural radioactivity.The result of analysis indicates that governance of associated minerals needs to be heeded.