载体ZrO2对Ru基催化剂氢解丙三醇催化性能的影响

来源 :第九届全国无机化学学术会议 | 被引量 : 0次 | 上传用户:netcapo
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  随着清洁高效的生物柴油作为替代能源大规模应用,丙三醇作为其副产物也将大量产生.将丙三醇转化为用途广泛、附加价值高的丙二醇,具有重要的现实意义[1].Ru、Rh、Pt、Ir、Pd或Cu等为活性组分的催化剂对丙三醇催化氢解转化为丙二醇有较高的活性和选择性[2].助剂组分和载体成分对催化剂的催化性能有很大的影响[3],而相同的载体,其制备方法不同也会对催化剂的性能产生影响.
其他文献
高半胱氨酸(Hcy)是重要的生物分子,在新陈代谢和内稳态过程中扮演非常重要的角色.Hcy与人类的心血管疾病、进行性老年痴呆症有直接关联,血清内高半胱氨酸的高水平是心血管疾病的风险因子,因此高灵敏度和专一性检测高半胱氨酸具有重要的研究意义.磷光铱配合物相比其他荧光材料,具有光稳定性好、发光效率高和发光颜色可调的优点.因此,我们设计与合成了近红外发射的磷光铱配合物探针NIR-Ir,通过铱配合物的醛基与
有机/无机杂化半导体材料是一类具有广阔应用前景的功能材料[1],由于可以通过选择不同的有机组元和无机组元来调控材料的性质,使得它们在分子开关、绿色照明、场效应管、非线性光学、光催化和太阳能电池等领域都展现出美好的前景。
A large number of crystal structures have been evaluated during the last two decades and a series of frequently recurring hydrogen-bonded synthons or motifs have been identified [1-4].
In the past decades,the self-assembly of coordination polymer(CPs)have been given considerable attention owing to their intriguing topologies and potential applications in gas adsorption/separation,ma
It is a challenge to develop magnetic materials with controllable function.
Copper complexes play important roles for developing functionalized materials owing to their rich properties such as catalysis,optics,and magnetism.[1,2] While the properties of complexes are associat
A new microporous negatively charged MOF,FJI-C2,was successfully synthesized by a solvethermal method,and structurally characterized using a variety of different technique,including X-ray diffraction(
In this report,Ni and TiO2 are embedded into porous carbon aerogel(CA)(donated as Ni-TiO2@CA)and studied their effects on the dehydrogenation properties of LiBH4.Ni@CA,TiO2@CA and CA are also investig
Supercapacitor,also known as electrochemical capacitor or ultracapacitor,has attracted growing interests because of its high power density,fast delivery rate and long cycle life,which plays an importa
The NH2/Mesoporous materials adsorbents were prepared by directly mixing of sodium silicate with 3-aminopropyltriethoxysilane(APTES)at the different conditions.Amino-functionalized mesoporous material