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Solvothermal reactions of Pb(OAc)2·2H2O with 4,4-azodibenzoic acid(H2L)in DMSO(DMSO = dimethyl sulfoxide)and DMF/H2O(DMF = N,N-dimethylformamide)at 90°C gave rise to two Pb(Ⅱ)coordination polymers [PbL(DMSO)]n(1)and [PbL(H2O)]n(2).