Concerning the key issues of sustainable chemistry,the utilization of abundant and sustainable alcohols for chemical production is highly desirable.
三价有机膦及其衍生物已广泛地应用在有机合成反应中,包括Wittig 反应、Staudinger 反应以及Mitsunobu 反应等;同时这些化合物也作为金属的配体应用到金属催化中,有机膦催化剂已作为一类重要的有机催化剂,被应用Morita-Baylis-Hillman/aza-Morita-Baylis-Hillman反应、Rauhut-Currier 反应、Michael(γ)加成反应以及关环反
次氯酸(次氯酸根)是活性氧重要组分,主要由活化的中性粒细胞和巨噬细胞产生,正常水平的次氯酸对于机体抵御外来病原体的入侵具有免疫作用,但次氯酸水平过高会引发氧化应激、对机体造成损伤.
惰性C-H 键的官能化研究成为有机化学研究热点之一,由于其独特的魅力和挑战性,被誉为"化学的圣杯".我们小组主要致力于发展采用光氧化还原催化以及后过渡金属催化实现惰性C-H 键官能化反应.
大自然广博深奥,人类对其进行的探索和认知永无止境.近年来,我们通过分子开关和智能响应功能材料的研究,不断加深对部分自然奥秘的领悟,首先发现缺陷态引起的电子旋风现象,有望对深入理解植物光合作用中叶绿体如何高效将水分解成为氧气和质子的机制提供启示;首次展示了力与酸碱度改变和分子间链式质子转移的关联,为在分子层面上深入理解触觉神经电信号传导提供了新思路;首次将电致自由基离子作为原位酸碱用于光电显示,同时
Over the past several decades,radical chemistry has been at the forefront of research in organic synthesis due to its generally mild reaction conditions,high functional group tolerance and unique sele
H-phosphonates play a major role in the research and application of the organic phosphorus chemistry[1].
A novel and efficient method to construct the pyrazolo[5,1-a]isoindole scaffold1-3 via a one-pot three-component cascade reaction of 1-(2-bromophenyl)buta-2,3-dien-1-one with hydrazine and isocyanide
An efficient protocol for synthesis of benzofulvene derivatives from easily available diarylacetylenes has been developed.
The indole skeleton and indole-containing polycyclic compounds,which constitute the core structure of numerous alkaloid and natural molecules,show distinct biological and pharmaceutical activity.