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This study comprises the synthesis, characterization and hydration behavior of pure and doped C2S (Ca2SiO4;C=CaO S=SiO2.).The samples were synthesized via the Pechini method at 800℃ for 2h.Products were analyzed and characterized with X-ray powder diffraction, thermogravimetry, BET, density measurements and Raman spectroscopy.The hydration behavior at standard conditions (23℃, lbar) was investigated with heat flow calorimetry.Reactivity at hydrothermal conditions (200℃, 16bar) was tested using laboratory autoclaves.In situ hydration studies under hydrothermal conditions were also performed with time and temperature resolved XRD in transmission mode at the SUL-X beamline of the ANKA Synchrotron radiation facility (Karlsruhe) in a specially designed reaction cell.