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We found that 2mol%potassium doped PbQ(Q = Te,Se,S)compounds have low thermal conductivity and therefore show good thermoelectric performance,especially in the PbSe+K systems.In microstructure observation by means of electron microscopy,we found a high-density nanoscale grain and precipitate distribution in the samples.Combining with numerical studies [2],we try to find the detailed correlation between the thermal transport properties and the microstructure change of the samples.