【摘 要】
：
Metal-organic frameworks(MOFs)have attracted much attention due to a unique combination of properties,such as extremely high surface areas,crystalline open structures,tunable pore size,and functionali
【机 构】
：
State Key Laboratory of Fine Chemicals,PSU-DUT Joint Center for Energy Research,School of Chemical E
【出 处】
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The 7th Sino-US Conference of Chemical Engineering(第7届中美化学工程
论文部分内容阅读
Metal-organic frameworks(MOFs)have attracted much attention due to a unique combination of properties,such as extremely high surface areas,crystalline open structures,tunable pore size,and functionality.These features make them as prospective materials in gas storage,catalysis and separation [1-3].Metallic components are essential parts in all MOFs structures.In most cases,these metal ions are blocked by solvent molecules,when removed,leaving free positions available for substrate chemisorption.Based on our groups early research [4],we prepared MOFs contain iron.Catalytic properties of NH2-MIL-53(Fe),MIL-53(Fe)and MIL-1O1(Fe)in the oxidation of phenol with hydrogen peroxide have been explored.All catalysts allow phenol oxidation under mild conditions(latm,25℃).The stability of the catalytic system and conversion of chemical oxygen demand(COD)have also been tested.
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