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Silver-polyaniline/polyamide 6 (Ag-PANI/PA6) composite nanofibers were prepared via the electrospinning process with a PA6/formic acid solution and the in-situ polymerization of PANI doped with HCl on the surface of the PA6 nanofibers and a sputtering-deposition process with a high purity Ag sputtering target at last.