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A convenient procedure for the preparation of functionalized BODIPYs bearing both F and an organo substituent at the boron center,using one-pot reactions between in situ formed dipyrromethenes and organotrifluoroborate salts,has been reported.The complexation reaction utilizes stable and commercial accessible organotrifluoroborate potassium salts and provides a facile access to a variety of novel B-functionalized BODIPYs,which are hard to access through current synthetic methods.