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With 1-Nitro-5,5-dioxo-5H-dibenzo [b,d]thiophene-3,7-dicarboxylic acid(H2SNBPDC)as the bridging ligands,two metal-organic frameworks {[Zn6(OH)2(NSBPDC)5(H2O)2]·X(sol)}n(1)and {[Mn3(NSBPDC)3(H2O)4]·x(sol)}n(2)have been solvothermally synthesized.