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研究背景:金属有机配合物在催化异戊二烯聚合中显示了良好的活性与选择性.大部分金属有机配合物催化体系得到的是顺式1,4–或3,4–聚异戊二烯,相比之下,可得到反式1,4–聚异戊二烯的反应体系还鲜有报道[1],相关机理研究更是有限.
含配位侧臂的单茂稀土金属配合物催化合成反式1,4-聚异戊二烯的理论研究
【摘 要】
：
研究背景:金属有机配合物在催化异戊二烯聚合中显示了良好的活性与选择性.大部分金属有机配合物催化体系得到的是顺式1,4–或3,4–聚异戊二烯,相比之下,可得到反式1,4–聚异戊二烯的反应体系还鲜有报道[1],相关机理研究更是有限.
【机 构】
：
大连理工大学化工与环境生命学部,大连 116024 Organometallic Chemistr
【出 处】
：
第十四届全国均相催化学术讨论会
【发表日期】
：
2015年7期
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