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A polymer-grafted SrA12O4: Eu2+, Dy3+ (PG-SAO-ED) were synthesized by using a bi-functional ligand (APD) as a bridge, which can coordinate with the unsaturated metal ions on the surface of SrA12O4: Eu2+, Dy3+ (SAO-ED) at one end, and copolymerize with methyl methacrylate and styrene at the other end.The luminescence properties of APD coordinated SAO-ED and PG-SAO-ED were analyzed by spectrometer (Konica Minolta LS-100) and spectrophotometer (F-4500 FL).The Mw and PD of the grafted polymer were measured by GPC and the contents of polymers in PG-SAO-ED were measured by TGA.