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Interface polarization and interface zone have been widely utilized to account for the abnormallyimproved dielectric properties of composites although their formation is rather vague and theirinfluence has never been directly measured.In this work, microα-SiC was designed as the fillerparticles incorporated into poly(vinylidenefluoride-co-chlorotrifluoroethylene) with internal doublebonds (P(VDF-CTFE-DB)) to construct polymer micro composites through solution castingmethod.