A High Performance K0.46Fe2.08(CN)6·3H2O@CNT as an Anode Material for Lithium ion Battery

• 作 者: HaiyingChe[1]WeiminZhang[2]XiaozhenLiao[2]ZifengMa[2]
• 机 构: School of Chemistry and Chemical Engineering,Shanghai Jiao Tong University,Shanghai,200240,China
• 出 处: 第十五届全国有机电化学与电化学工业学术会议
• 发表日期: 2016年期

　　Prussian blue and its analogues have been attractive in modern electrochemical reversible energy storage systems.However,the study of Prussian blue analogues as anode materials for lithium-ion batteries so far is very limited.Herein,Prussian blue analogue(PBA)and carbon nano tube compound anode,K0.46Fe2.08(CN)6·3H2O@CNT(PBA@CNT),were synthesized via a low-cost and simple solution precipitation method.The compound exhibited excellent cycling stability with no capacity loss even after 400 cycles at a specific capacity of around 400 mAh g-1.Furthermore,superior rate capability of 405 mAh g-1 and 208 mAh g-1 were obtained when the discharge current density at 500 and 2500 mA g-1 respectively due to the nano particle sizes,open-framework structure of the PBA,the dispersion,and the high conductivity of carbon nano tubes.In brief,the PBA@CNT compound displays excellent electrochemical performance and is highly promising for further study.