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Porous solids are of scientific and technological interest because of a wide range of emerging applications.Up to now, soft or hard templating route is still the major synthetic strategy to create high-surface-area meso-or macroporous inorganic materials.However, these strategies suffer some disadvantages such as low crystallinity, tedious synthesis process, employing undesirable reagent (i.e.HF) and hardly producing mesostructure with ultrathin wall.