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Lanthanide(Ⅲ) coordination polymers have potential applications as functional materials especially in photoluminescence1, sensor2, and magnet3.Based on the flexible coordination of tetrazole, In this study, a 1D Eu(Ⅲ) coordination polymer [Eu(TZI)(5H2O)]n (1) (5-H3TZI=5-tetrazolylisophthalic acid) has been hydrothermally synthesized.The luminescent properties of 1 indicate that 1 has a strong red luminescent emission.