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The thermal decomposition behavior of 4,6-Dinitro-5,7-diamino benzenfuroxan（CL-14） was measured using a C-500 type Calvet Micro-calorimeter at four different temperatures under atmospheric pressure.The apparent activation energy and pre-exponential factor of the exothermic decomposition reaction are 270.06kJ mol-1 and 1021.5 s-1,respectively.