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金属羰基在多种催化反应中起关键作用(如CO 氧化、费托合成、甲醇合成等）[1],因此金属羰基物种的研究对催化反应机理具有重要意义.许多金属(铁、镍、铑、钌）都能生成稳定羰基物种[2].然而,锌为甲烷羰基化[3]等重要催化反应的活性组分,锌羰基物种生成的报道很少.
ZnZSM-5上稳定锌羰基及其氢化反应的固体NMR研究
【摘 要】
：
金属羰基在多种催化反应中起关键作用(如CO 氧化、费托合成、甲醇合成等）[1],因此金属羰基物种的研究对催化反应机理具有重要意义.许多金属(铁、镍、铑、钌）都能生成稳定羰基物种[2].然而,锌为甲烷羰基化[3]等重要催化反应的活性组分,锌羰基物种生成的报道很少.
【机 构】
：
中国科学院武汉物理与数学研究所,波谱与原子分子物理国家重点实验室,武汉磁共振中心,武汉430071
【出 处】
：
第十五届全国青年催化学术会议
【发表日期】
：
2015年7期
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