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Perovskite solar cells(PSCs)have experienced sharp development and emerged as a superstar in the field of photovoltaics in recent years.We introduces two kinds of dyes,zinc porphyrin(YD2-o-C8)and cis‐di(thiocyanato)bis(2,2‐bipyridyl4,4‐ dicarboxylate)ruthenium(Ⅱ)(denoted as N719)to enable highly efficient and highly stable perovskite solar cells.