The effect of the trans axial ligand of cobalt corroles on water oxidation activity in neutral aqueo

来源 :2017年中西部地区无机化学化工学术研讨会 | 被引量 : 0次 | 上传用户:ciximdt
下载到本地 , 更方便阅读
声明 : 本文档内容版权归属内容提供方 , 如果您对本文有版权争议 , 可与客服联系进行内容授权或下架
论文部分内容阅读
  A series of cobalt complexes of 5,10,15-tris(pentafluorophenyl)-corrole [Co(tpfc)](1)with various axial ligands were synthesized and examined as single-site catalysts for water oxidation.
其他文献
  Triruthenium dodecacarbonyl(Ru3(CO)12)as a potent catalyst precursor showed the unique activity for homogeneous catalytic reactions,such as silylation[1],hy
会议
  二茂铁及其衍生物因具有优异的燃烧调节功能,被广泛应用于各种复合推进剂当中。截止目前,商品化的二茂铁燃速催化剂虽然可以提高丁羟等推进剂的燃速,但是它们在推进剂的贮存
  Sonogashira反应是芳基卤化物和末端炔之间的偶联,被常用于构建Csp2-Csp键。合成芳基炔和共轭烯化合物被广泛的应用于天然产物、药物以及有机材料等方面。于是一代又一代
  第IVB族的茂金属化合物稳定性好,可通过配体调控茂金属中心催化活性,是一类极具应用前景的Lewis酸催化剂。我们前期研究发现,水杨酸茂钛配合物可高效催化三组分的Mannich反
  Reported herein is the new application of ionothermal synthesis for inorganic optical materials.Under ion othermal conditions with different imidazolium ion
会议
  A general preparative route in ionic liquids for crystalline halogeno(cyano)cuprate multifunctional materials is developed in this work.
会议
  离子热合成是一种以离子液体(ILs)为反应介质的环境友好型制备方法[1]。低共熔混合物(DESs)为一类重要的ILs,可通过控制其组分种类、比例等条件调控目标材料的结构与性能
  Due to the discovery of high-symmetry rare-earth hexanuclear SBU,controllable design and assembly REOFs have become feasible.
会议
  The water-soluble copper(Ⅱ)complex of the pincer ligand L is a single-site water oxidation catalyst in aqueous solutions.The homogeneous catalysis was conf
会议
  Three cobalt complexes of 5,10,15-tris(pentafluorophenyl)corrole(1)and 5,15-bis-(pentafluorophen yl)-10-(4)-(1-pyrenyl)phenylcorrole(2)with pyridine(py)and
会议