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Solution precursor plasma spraying (SPPS) was employed to prepare porous YSZ/LSM composite cathode for solid oxide fuel cells (SOFCs).The surface morphology and microstructure of the YSZ/LSM deposits were characterized by SEM.The electrochemical behavior was investigated through the impedance spectroscopy.The effect of annealing treatment on SPPS YSZ/LSM microstructure and cathode polarization was examined.