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A porous three-dimensional framework {[Cu3(L)3(H2O)3](H2O)7}n (1) is prepared by the reaction of CuCl2 and H2L (H2L= 5-(1-Oxo-1,3-dihydro-isoindol-2-yl)-isophthalic acid) in a mixed solution of CH3OH,H2O and DMF.