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A novel Cd(Ⅱ)-based coordination polymers {[Cd2(C26H19NO12)(H2O)]·2H2O}n(1) has been successfully synthesized by Cd(NO3)2·4H2O and 5-[N,N-bis(5-Methylisophthalic acid)amion] isophthalic acid through hydrothermal method.The structure of the compound 1 was characterized by IR、X-ray single crystal diffraction and X-ray powder diffraction.The solid fluorescence property of the compound 1 was further studied.