Hydrogen Bond-Directed Supramolecular Structure of [Cd(Him)4(H2O)2] [Cd(Him)4(2,6-nds)2] (Him=imidaz

• 作 者: DengDong-Sheng;JIBao-Ming;
• 机 构: College of Chemistry and Chemical Engineering,Luoyang Normal University,Luoyang 471022,China
• 出 处: 2008年中西部地区无机化学、化工学术交流会
• 发表日期: 2008年期

A novel complex, C44H48O8N16S2Cd2, namely, [Cd(Him)4(H2O)2][Cd(Him)4(2,6-nds)2] (Him=imidazole, 2,6-nds=2,6-naphthalenedisulfonate)], has been synthesized and structurally characterized by single-crystal X-ray diffraction. The complex crystallizes in a typical hybrid organic-inorganic pattern, and the sulfonate coordinated directly to Cd2+. Moreover, the sheet structure was formed through O-H…O and N-H…O hydrogen bonds.