【摘 要】
：
酰胺的合成在有机化学及生物化学的化学键转化中有着极重要的价值，在药物化学、天然产物、多肽及材料制造方面有着广泛应用。传统合成酰胺的方法有较多的制约因素，而且现代有机合成推崇原子经济性和绿色化学的理念。近年来，过渡金属催化剂包括铑、钯、铟、铱、钌等配合物均已成功应用到伯酰胺的合成中[1]。我们设计并合成新型的离子型钌钳形化合物，成功应用到醛肟重排转化成伯酰胺的过程中，产率达到99％；同时可以通过一锅
【机 构】
：
郑州大学化学与分子工程学院,河南郑州高新区科学大道100号,450001 中原油田钻井工程技术研究
论文部分内容阅读
酰胺的合成在有机化学及生物化学的化学键转化中有着极重要的价值，在药物化学、天然产物、多肽及材料制造方面有着广泛应用。传统合成酰胺的方法有较多的制约因素，而且现代有机合成推崇原子经济性和绿色化学的理念。近年来，过渡金属催化剂包括铑、钯、铟、铱、钌等配合物均已成功应用到伯酰胺的合成中[1]。我们设计并合成新型的离子型钌钳形化合物，成功应用到醛肟重排转化成伯酰胺的过程中，产率达到99％；同时可以通过一锅煮的方法直接由醛得到酰胺并取得较高的产率[2]。
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