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Two β-carboline ruthenium(Ⅱ)complexes,namely,[Ru(L)2(Cl-Ph-βC)](PF6),where N-N = 4,4-dimethyl-2,2-bipyridine(dmb,Ru 1),2,2 bipyridine(bpy,Ru 2),and Cl-Ph-βC(Cl-phenyl-9H-pyrido[3,4-b]indole)were synthesized.