利用超快光谱研究量子点与MV2+之间的热电子转移

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在量子点太阳能电池中,太阳光激发量子点产生光激发电子,这部分电子快速转移给电子受体比如说TiO2,从而有效地产生光电流[1].当激发光的能量大于量子点的能带隙时,会产生热电子与空穴对,它们会迅速弛豫到带边,与此同时,多余的能量以声子的形式损耗掉,传统的太阳能电池就是把处在带边的电子和空穴抽取出来形成电流.然而,在热电子与空穴弛豫到带边这个过程中,有很大一部分太阳能散失掉了,如果这些能量可以被充分利用起来,那么光电转换效率就可以大幅度的提高,理论上可以达到66%[2],基于此,对热电子转移的研究越来越重要.
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