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To achieve a nanoscopic dispersion of nanoparticles(NPs) together with a tunable inter-particle separation distance of NPs is still a great challenge for the technological application of polymer nanocomposites(PNCs).Herein, Through simulation we put forward a new and achievable approach to design and prepare a nanoparticle chemical network, with the NPs acting as "giant cross-linkers" or netpoints to chemically connect the dual end-groups of each polymer chain to form a network.