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Development of highly active and stable electrocatalysts is a key to realize efficient hydrogen evolution through water electrolysis.Here,the development of a 3D self-supported integrated electrode constituting few layered N,P dual-doped carbon-encapsulated ultrafine MoP nanocrystal/MoP cluster hybrids on carbon cloth(FLNPC@MoP-NC/MoP-C/CC)is demonstrated.