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The development of non-precious metal-based electrocatalyst to replace Pt in fuel cells has become the goals of intensive research in recent years [1,2].In this paper,with Co(SO4) 7 H2O as the metal precursor and N,N-bis(salicylidene)ethylenediamine (Salen) as the nitrogen precursor,carbon-supported non-precious metal catalysts,CoSalen/C,were synthesized using a facile thermal annealing approach.