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The Neoproterozoic Riviera W-REE-Mo deposit is one of the largest unmined tungsten resources in the world and is associated with pervasively altered A-type granites of the Neoproterozoic Cape Granite Suite Western Cape, South Africa.The present study investigated the mineral chemistry of scheelite, the principal ore mineral with the aim to record the variation of solid solution molybdenum for geometallurgical purposes and also as an indicator of changing redox conditions of the mineralizing hydrothermal fluids.