Visible light-driven water splitting into oxygen and hydrogen is an appealing pathway to convert solar energy into fuels.[1-2] In particular,photoelectrochemical cells(PECs)combining a photoanode wher
Seven new coordination polymers based on the redox-active tetra(4-pyridyl)-tetrathiafulvalene ligand and different transition metal ions,were synthesized and fully characterized.1 Complex 1 exhibits a
A new kind of organic-inorganic hybrid compound [(PMo12O40)(C5H8N)3] was synthesized under hydrothermal conditions and characterized by single crystal X-ray diffraction,IR,fluorescence,UV and elementa
The hexamethylenetetramine(hmt)reacted with Cd(Ⅱ),Ag(Ⅰ),and Zn(Ⅱ)salts of carboxylic acids resulted in the formation of six novel coordination architectures,[Cd(hmt)2(L1)2H2O],1(L1 = 1,3-benzodioxole-
New heteronuclear Zn2Ln2 clusters [Zn2L2Ln2(hfac)6)](Ln = La(1),Eu(2)and Tb(3))have been synthesized based on a flexible Schiff base(H2L = N,N-bis(salicylidene)-3,6-dioxa-1,8-diaminooctane)and β-diket
Four novel three dimensional(3D)3d-4f heterometallic coordination polymers,namely,[Ln12Cu31I27(ina)34(NDC)3(H2O)12]n.2nH2O [Ln = Sm(1),Eu(2),Gd(3),Tb(4); NDC = 1,4-naphthalenedicarboxylate,Hina = ison
Solvothermal reaction of Manganese(Ⅱ)salt with monosodium 2-sulfoterephthalate(2-NaH2stp)and two multi-pyridine N-containing auxiliary ligands results in the formation of two new complexes formulated