Synthesis of W-Fe-S clusters with heteroligated core toward structural mimicking of nitrogenase FeMo

• 作 者: Xu-DongChen[1]RichardH.Holm[2]
• 机 构: College of Chemistry and Materials Science,Nanjing Normal University,Nanjing,Jiangsu 210023,Chnia
• 出 处: 第九届全国无机化学学术会议
• 发表日期: 2015年期

　　The microbial transformation of dinitrogen to biologic available form such as ammonium is called biological nitrogen fixation(BNF),which is mediated by nitrogenase.The FeMo-cofactor is believed to be the key catalytic center in the most-studied class of nitrogenase.